The most poisonous substance currently used as a rocket engine propellant is hydrazine (N2H4) and its variants (the most commonly used being Unsymmetrical Dimethylhydrazine, or UDMH). Animal studies have put the median lethal dose for hydrazine at around 60 mg/kg (meaning that an average adult could be killed by just 4.2 grams), and the CDC classify it as "Immediately Dangerous to Life or Health" at gas concentrations of anything higher than 15 parts per million.
Hydrazine can be absorbed into the body through skin contact, ingestion or inhalation. Exposure to hydrazine vapour causes skin burns, irritation to the eyes and mouth, vomiting, bleeding in the lungs and sometimes seizures. In the long term, exposure has been linked to liver and kidney damage, nerve damage (including tremors) and several different cancers.
Unsurprisingly for rocket fuel, hydrazine is also extremely flammable. It is what is called a "hypergolic" fuel, meaning that it ignites on contact with its oxidizer (typically dinitrogen tetroxide, but also sometimes the almost-as-toxic red-fuming nitric acid). It also ignites on contact with most acidic substances, many kinds of metal, and porous materials such as cloth or wood. Its flames are extremely hot, but totally transparent, and therefore invisible to the human eye.
The first vehicle to use hydrazine was the German Me-163 rocket-powered fighter aircraft. While the rocket provided excellent performance, fuel leaks and accidental explosions reportedly killed more pilots than enemy action. The combination of UDMH and RFNA was referred to as "devil venom" by Soviet engineers. It apparently smells of fish, but but getting close enough to smell it is extremely inadvisable.
Despite its many risks, hydrazine and its derivatives are still used because they are generally stable over a wide range of temperatures when stored correctly, burn cleanly and can function as monopropellants (fuels that don't require an oxidizer) when catalysed with iridium. Today hydrazine is most commonly used in monopropellant manoeuvring thrusters on spacecraft.
Although unpleasant, hydrazine and its derivatives are not exceptionally toxic relative to other proposed propellants. In the 1960s and 1970s, for example, engineers in search of performance improvements tried fuelling rockets with a mixture of the highly toxic chlorine trifluoride and hydrogen, a combination that created an exhaust plume of hydrofluoric acid. Other ideas that have been tried include injecting mercury into the combustion chamber as an additive.
The most poisonous substance currently used as a rocket engine
rocket engine
Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordance with Newton's third law. Most rocket engines use the combustion of reactive chemicals to supply the necessary energy, but non-combusting forms such as cold gas thrusters and nuclear thermal rockets also exist.
It is extremely toxic, highly flammable, and highly corrosive. MMH has greater compatibility with metals as compared to N 2O4 as a result of its corrosive properties.
Devil's venom was a nickname coined by Soviet rocket scientists for a liquid rocket fuel composed of a dangerous combination of red fuming nitric acid and a hydrazine derivative — specifically, hypergolic UDMH-nitric acid.
Hydrazine exposure has toxic effects on multiple organ systems, including the neurological, hematological, pulmonary, dermatologic, and hepatic systems. Hydrazines produce a functional pyridoxine deficiency by inhibiting its synthesis by deactivating key coenzymes.
Completely depends on the rocket. Falcon 9 burns kerosene, so in principle it would be no more toxic than being around a plane or a bunch of cars. Many hypergolic fuels, which some launch vehicles and spacecraft use, can be wicked toxic though.
The most poisonous substance currently used as a rocket engine propellant is hydrazine (N2H4) and its variants (the most commonly used being Unsymmetrical Dimethylhydrazine, or UDMH).
DANGEROUS FIRE and EXPLOSION HAZARD. ► Hydrazine can self-ignite at low temperatures. OSHA: The legal airborne permissible exposure limit (PEL) is 1 ppm averaged over an 8-hour workshift.
Hydrazine is also used as rocket fuel propellant. Mixing it with oxidising agent dinitrogen tetroxide, N2O4, creates a hypergolic mixture – a mixture so explosive, no ignition is required. As the fuel burns, three reactions take place, decomposing hydrazine into ammonia, nitrogen and hydrogen gases.
Hydrazines (H₂NNH₂) are clear, colorless liquids with an ammonia-like odor. Hydrazines are highly reactive and easily catch fire. Workers may be harmed from exposure to hydrazine.
SpaceX's future rocket Starship, for example, uses a mix of liquid methane and liquid oxygen propellants. Still, any hydrocarbon fuel produces some amount of soot. And even “green rockets,” propelled by liquid hydrogen, produce water vapor, which is a greenhouse gas at these dry high altitudes.
Raptor is a family of rocket engines developed and manufactured by SpaceX. A notable trait of this engine family is the use of a full-flow staged combustion cycle (FFSC). They are powered by cryogenic liquid methane and liquid oxygen, a mixture known as methalox.
This time around they used water, a lot of water which is typical of other launches by the rest of the world to attenuate rocket engine noise. It also does wonders for the launch pad. So the extra stuff is water particles and steam ... Water condensing out of the air because of the cryo fuel.
Common hypergolic propellant combinations include: Aerozine 50 + nitrogen tetroxide (NTO) – widely used in historical American rockets, including the Titan II; all engines in the Apollo Lunar Module. Aerozine 50 is a mixture of 50% UDMH and 50% straight hydrazine (N2H4).
UDMH is a highly toxic compound exhibiting irritant, hepatotoxic, and neurotoxic properties. In this study, the toxic effect of heptyl on isolated rat heart and lymphatic vessels was demonstrated.
Symptoms of acute (short-term) exposure to high levels of hydrazine may include irritation of the eyes, nose, and throat, dizziness, headache, nausea, pulmonary edema, seizures, and coma in humans. Acute exposure can also damage the liver, kidneys, and central nervous system in humans.
Health effects related to jet fuel exposures may include irritation to unprotected skin, eye and upper respiratory irritation, fatigue, breathing difficulty, headaches, dizziness, and sleep disturbances. Drinking jet fuels is dangerous and may result in convulsions, coma and even death.
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